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Water Pollution & Wastewater Treatment (Environmental Sciences) Solved Questions & Notes (2026) - Apex Rankers

Environmental Sciences & Management > Environmental Sciences > Water Pollution & Wastewater Treatment

50 Total Solved Questions
~75 mins Estimated Reading Time
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Water Pollution & Wastewater Treatment

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Q. 1 Environmental Sciences
Difficulty: Medium (1 Mark)
In the Streeter-Phelps dissolved oxygen sag model, what two opposing kinetic processes govern the dissolved oxygen (DO) profile downstream of an organic wastewater discharge?
A
Deoxygenation (BOD exertion) and atmospheric reaeration
✓ Correct
B
Sedimentation and photolysis
C
Nitrification and methanogenesis
D
Evapotranspiration and chemical precipitation
💡 Step-by-Step Explanation & Concept Rationale
The Streeter-Phelps equation balances the rate of dissolved oxygen depletion due to microbial biochemical oxygen demand (deoxygenation rate constant k1) against the rate of oxygen replenishment across the air-water interface (reaeration rate constant k2).
Q. 2 Environmental Sciences
Difficulty: Easy (1 Mark)
What does the 'Critical Point' on a dissolved oxygen (DO) sag curve represent?
A
The point of maximum stream temperature
B
The point of lowest dissolved oxygen concentration (maximum oxygen deficit)
✓ Correct
C
The discharge point where BOD is highest
D
The point where all fish populations completely recover
💡 Step-by-Step Explanation & Concept Rationale
The critical point on the DO sag curve represents the location downstream where the deoxygenation rate equals the reaeration rate, resulting in the minimum dissolved oxygen concentration (critical oxygen deficit, Dc) and the highest stress on aquatic life.
Q. 3 Environmental Sciences
Difficulty: Easy (1 Mark)
Why is Chemical Oxygen Demand (COD) virtually always higher than 5-day Biochemical Oxygen Demand (BOD5) for the same wastewater sample?
A
COD measures only volatile suspended solids
B
Dichromate chemical oxidation breaks down both biodegradable and non-biodegradable refractory organic matter
✓ Correct
C
BOD5 is measured at 100°C while COD is measured at 20°C
D
COD measures only inorganic minerals
💡 Step-by-Step Explanation & Concept Rationale
COD uses a strong chemical oxidant (potassium dichromate in concentrated sulfuric acid) that completely oxidizes nearly all organic carbon (both biologically degradable and refractory/toxic compounds), whereas BOD5 measures only the fraction biologically degraded by aerobic bacteria over 5 days.
Q. 4 Environmental Sciences
Difficulty: Hard (1 Mark)
In the standard 5-day Biochemical Oxygen Demand (BOD5) test, what chemical reagent is routinely added to inhibit the exertion of nitrogenous biochemical oxygen demand (NBOD)?
A
2-chloro-6-(trichloromethyl)pyridine (TCMP) or allylthiourea
✓ Correct
B
Mercuric sulfate
C
Potassium permanganate
D
Sodium thiosulfate
💡 Step-by-Step Explanation & Concept Rationale
To measure Carbonaceous BOD (CBOD5) without interference from nitrifying bacteria oxidizing ammonia to nitrite/nitrate, a nitrification inhibitor such as TCMP or allylthiourea (ATU) is added to the incubation bottle.
Q. 5 Environmental Sciences
Difficulty: Medium (1 Mark)
What is the typical BOD5/COD ratio for untreated municipal domestic sewage?
A
0.05 to 0.10
B
0.40 to 0.60
✓ Correct
C
0.85 to 0.95
D
1.50 to 2.00
💡 Step-by-Step Explanation & Concept Rationale
Untreated domestic wastewater typically has a BOD5/COD ratio between 0.40 and 0.60, indicating that a substantial portion of the organic matter is readily biodegradable. Ratios below 0.3 indicate refractory or toxic industrial waste requiring specialized treatment.
Q. 6 Environmental Sciences
Difficulty: Easy (1 Mark)
What physical phenomenon occurs during 'Cultural Eutrophication' of a freshwater lake following excessive runoff of synthetic agricultural fertilizers?
A
Sudden acidification of the epilimnion
B
Explosive proliferation of algal blooms followed by nocturnal and benthic oxygen depletion during bacterial decomposition
✓ Correct
C
Immediate precipitation of all dissolved calcium salts
D
Instantaneous evaporation of lake surface waters
💡 Step-by-Step Explanation & Concept Rationale
Cultural eutrophication is caused by anthropogenic nutrient enrichment (phosphates and nitrates), triggering massive algal blooms. When these algae die, heterotrophic bacteria consume dissolved oxygen during decomposition, creating profound hypoxia (<2 mg/L DO) and fish kills.
Q. 7 Environmental Sciences
Difficulty: Hard (1 Mark)
Which cyanobacterial hepatotoxin, frequently produced by freshwater blooms of Microcystis aeruginosa, poses severe risks of liver damage and carcinogenicity in drinking water supplies?
A
Microcystin-LR
✓ Correct
B
Saxitoxin
C
Tetrodotoxin
D
Aflatoxin B1
💡 Step-by-Step Explanation & Concept Rationale
Microcystin-LR is a potent cyclic peptide hepatotoxin produced by bloom-forming cyanobacteria (Microcystis, Anabaena, Planktothrix). The WHO provisional drinking water guideline limit for total microcystin-LR is 1.0 ug/L.
Q. 8 Environmental Sciences
Difficulty: Medium (1 Mark)
In conventional water treatment plants, what is the primary role of rapid chemical coagulation using alum (aluminum sulfate, Al2(SO4)3·14H2O)?
A
To kill pathogenic viruses through osmotic pressure
B
To neutralize the negative surface electrostatic charges (zeta potential) of colloidal particles, allowing them to aggregate
✓ Correct
C
To dissolve calcium and magnesium scale
D
To increase dissolved oxygen saturation
💡 Step-by-Step Explanation & Concept Rationale
Natural colloidal particles carry negative surface charges that repel each other, keeping them suspended. Coagulants like alum provide trivalent aluminum cations (Al3+) that compress the electrical double layer and neutralize zeta potential, enabling particle agglomeration.
Q. 9 Environmental Sciences
Difficulty: Medium (1 Mark)
What is the biological layer of active microorganisms that forms on the surface of a slow sand filter and performs the primary filtration and pathogen purification called?
A
Bio-floc
B
Schmutzdecke (hypogeal biological film)
✓ Correct
C
Activated cake
D
Zeolite crust
💡 Step-by-Step Explanation & Concept Rationale
In slow sand filtration, a gelatinous biological biofilm known as the 'Schmutzdecke' develops on the top sand layer. It consists of bacteria, protozoa, algae, and extracellular polysaccharides that trap particles and bio-oxidize pathogens with 99.9% removal efficiency.
Q. 10 Environmental Sciences
Difficulty: Medium (1 Mark)
In water chlorination chemistry, what chemical species are collectively referred to as 'Free Available Chlorine'?
A
Hypochlorous acid (HOCl) and hypochlorite ion (OCl-)
✓ Correct
B
Monochloramine (NH2Cl) and dichloramine (NHCl2)
C
Sodium chloride (NaCl) and chlorate (ClO3-)
D
Trihalomethanes (THMs)
💡 Step-by-Step Explanation & Concept Rationale
When chlorine gas or hypochlorite dissolves in pure water, it hydrolyzes to form hypochlorous acid (HOCl) and hypochlorite ions (OCl-), which together constitute 'Free Available Chlorine'. HOCl is ~80 times more effective as a germicide than OCl-.
Q. 11 Environmental Sciences
Difficulty: Hard (1 Mark)
Why is disinfection with hypochlorous acid (HOCl) significantly more effective at pH 6.5 to 7.0 than at pH 8.5?
A
At higher pH, chlorine precipitates as calcium hypochlorite crystals
B
At lower pH, the uncharged, highly germicidal HOCl molecule predominates over the negatively charged OCl- ion
✓ Correct
C
At higher pH, chlorine evaporates into the atmosphere
D
Acidic conditions destroy all bacterial endospores instantly
💡 Step-by-Step Explanation & Concept Rationale
HOCl is a weak acid (pKa ~7.54 at 25°C). Below pH 7.5, uncharged HOCl predominates, readily diffusing through microbial cell membranes. Above pH 7.5, negatively charged hypochlorite (OCl-) dominates, which is repelled by the negative bacterial cell wall.
Q. 12 Environmental Sciences
Difficulty: Medium (1 Mark)
What harmful class of carcinogenic disinfection byproducts (DBPs) is formed when chlorine reacts with naturally occurring dissolved organic matter (humic and fulvic acids) in raw surface water?
A
Polycyclic aromatic hydrocarbons (PAHs)
B
Trihalomethanes (THMs, such as chloroform) and haloacetic acids (HAAs)
✓ Correct
C
Dioxins and furans
D
Polychlorinated biphenyls (PCBs)
💡 Step-by-Step Explanation & Concept Rationale
Free chlorine oxidizes natural organic matter (NOM) to generate halogenated disinfection byproducts, primarily Trihalomethanes (THMs: chloroform, bromoform, bromodichloromethane, dibromochloromethane) and Haloacetic Acids (HAAs), which are suspected carcinogens regulated under drinking water standards.
Q. 13 Environmental Sciences
Difficulty: Medium (1 Mark)
What wavelength of ultraviolet (UV) radiation is optimal for germicidal disinfection of drinking water and wastewater effluents by disrupting microbial DNA?
A
185 nm
B
254 nm (UV-C)
✓ Correct
C
365 nm (UV-A)
D
400 nm (Visible blue)
💡 Step-by-Step Explanation & Concept Rationale
Germicidal UV-C light peaking at 254 nm is maximally absorbed by nucleic acids (DNA/RNA) of bacteria and viruses, forming cyclobutane pyrimidine dimers (thymine dimers) that prevent transcription and replication.
Q. 14 Environmental Sciences
Difficulty: Easy (1 Mark)
In municipal wastewater treatment, preliminary treatment unit processes specifically include:
A
Bar screens, comminutors, and grit removal chambers
✓ Correct
B
Trickling filters and secondary clarifiers
C
Anaerobic digesters and sludge drying beds
D
Reverse osmosis membranes and carbon contactors
💡 Step-by-Step Explanation & Concept Rationale
Preliminary treatment physically removes coarse solids, rags, wood, plastic (via bar screens or comminutors), and heavy inorganic matter like sand, gravel, and coffee grounds (via grit chambers) to protect downstream pumps and pipelines.
Q. 15 Environmental Sciences
Difficulty: Medium (1 Mark)
What percentage of Total Suspended Solids (TSS) and Biochemical Oxygen Demand (BOD5) is typically removed in a properly operating primary sedimentation clarifier?
A
10-20% TSS and 5-10% BOD5
B
50-70% TSS and 25-40% BOD5
✓ Correct
C
95-99% TSS and 90-95% BOD5
D
100% TSS and 0% BOD5
💡 Step-by-Step Explanation & Concept Rationale
Primary sedimentation tanks rely on gravity settling to remove approximately 50% to 70% of settleable suspended solids (TSS) and 25% to 40% of particulate BOD5 before the effluent enters biological secondary treatment.
Q. 16 Environmental Sciences
Difficulty: Easy (1 Mark)
In the conventional Activated Sludge Process (ASP), what does the operational parameter 'MLSS' represent?
A
Maximum Liquid Sludge Settling
B
Mixed Liquor Suspended Solids (the concentration of suspended biomass and solids in the aeration basin)
✓ Correct
C
Minimum Leachate Solution Saturation
D
Mean Limnological Salinity Standard
💡 Step-by-Step Explanation & Concept Rationale
MLSS (Mixed Liquor Suspended Solids) is the concentration of suspended solids (including active microorganisms, inert organic matter, and inorganic ash) maintained in the biological aeration basin, typically ranging between 1,500 and 4,000 mg/L in conventional ASP.
Q. 17 Environmental Sciences
Difficulty: Medium (1 Mark)
In activated sludge operations, what operational problem is characterized by poor sludge settleability and compaction in the secondary clarifier, frequently caused by the overgrowth of filamentous bacteria (e.g., Sphaerotilus natans, Microthrix parvicella)?
A
Sludge bulking
✓ Correct
B
Sludge stripping
C
Thermal stratification
D
Breakpoint chlorination
💡 Step-by-Step Explanation & Concept Rationale
Sludge bulking occurs when filamentous bacteria proliferate excessively over floc-forming bacteria (due to low DO, low F/M ratio, or septic conditions), preventing flocs from compacting and causing biomass carryover into final effluent.
Q. 18 Environmental Sciences
Difficulty: Medium (1 Mark)
What parameter is commonly measured in an activated sludge laboratory to quantify the settling characteristics and compaction of biological sludge?
A
Sludge Volume Index (SVI, in mL/g)
✓ Correct
B
Total Dissolved Solids (TDS)
C
Jackson Turbidity Units (JTU)
D
Hardness
💡 Step-by-Step Explanation & Concept Rationale
The Sludge Volume Index (SVI) is the volume in mL occupied by 1 gram of activated sludge after settling for 30 minutes in a 1-liter graduated cylinder. An SVI between 80-120 mL/g indicates good settleability; SVI > 150 mL/g indicates sludge bulking.
Q. 19 Environmental Sciences
Difficulty: Hard (1 Mark)
The Food-to-Microorganism (F/M) ratio in an activated sludge reactor is mathematically expressed as:
A
kg BOD applied per day / kg MLVSS in aeration tank
✓ Correct
B
kg TSS / m³ water treated
C
kg Chlorine / kg Bacteria
D
Volume of tank / Inflow rate
💡 Step-by-Step Explanation & Concept Rationale
The F/M ratio (food-to-microorganism ratio) measures the organic loading rate relative to biological inventory: F/M = (Q × Influent BOD5) / (V × MLVSS), expressed in units of kg BOD5 per kg MLVSS per day (typically 0.2-0.5 for conventional ASP).
Q. 20 Environmental Sciences
Difficulty: Easy (1 Mark)
How does a Trickling Filter differ fundamentally in biological process mechanism from an Activated Sludge Process?
A
Trickling filters are attached-growth (fixed-film) bio-reactors, whereas activated sludge is a suspended-growth system
✓ Correct
B
Trickling filters operate without atmospheric oxygen
C
Activated sludge cannot remove dissolved organic matter
D
Trickling filters produce no waste sludge
💡 Step-by-Step Explanation & Concept Rationale
A trickling filter is an attached-growth (fixed-film) process where wastewater trickles over inert rock or plastic packing media covered by a stationary slime layer of microorganisms. Activated sludge is a suspended-growth biological system.
Q. 21 Environmental Sciences
Difficulty: Medium (1 Mark)
In wastewater stabilization pond systems, which pond type contains an aerobic upper layer driven by algal photosynthesis and an anaerobic benthic zone where settled organics undergo fermentation?
A
Facultative pond
✓ Correct
B
Maturation pond
C
Polishing pond
D
Dissolved air floatation cell
💡 Step-by-Step Explanation & Concept Rationale
A facultative stabilization pond exhibits three zones: an aerobic surface zone where algae supply dissolved oxygen through photosynthesis, an intermediate facultative layer, and an anaerobic bottom zone where anaerobic bacteria ferment settled sludge.
Q. 22 Environmental Sciences
Difficulty: Medium (1 Mark)
What is the primary role of tertiary 'Maturation Ponds' (polishing ponds) in wastewater lagoon series?
A
Primary grit settling
B
Pathogen reduction (die-off of fecal coliforms, viruses, and helminth ova via solar UV and high pH)
✓ Correct
C
Heavy oil removal
D
Anaerobic methane production
💡 Step-by-Step Explanation & Concept Rationale
Maturation (polishing) ponds are shallow (1.0-1.5 m), well-oxygenated tertiary lagoons designed primarily to achieve high pathogen removal (bacteria, viruses, helminths) through exposure to solar UV radiation, high dissolved oxygen, and alkaline pH (>9.0).
Q. 23 Environmental Sciences
Difficulty: Hard (1 Mark)
In the Modified Ludzack-Ettinger (MLE) biological nutrient removal process, how is biological nitrogen removal achieved?
A
An anoxic tank precedes the aerobic tank, utilizing internal nitrate recycle from the aerobic zone and influent BOD as carbon source for denitrification
✓ Correct
B
Pure oxygen gas is injected at high pressure to volatilize nitrogen
C
Wastewater is boiled to evaporate ammonium salts
D
Chlorine gas is bubbled into deep lagoons
💡 Step-by-Step Explanation & Concept Rationale
The MLE process places an anoxic zone ahead of the aerobic nitrification basin. Nitrified mixed liquor is recycled back from the aerobic tank to the anoxic tank, where denitrifying bacteria reduce NO3- to N2 gas using raw influent wastewater organics as electron donors.
Q. 24 Environmental Sciences
Difficulty: Medium (1 Mark)
In the anaerobic digestion of municipal sewage sludge, what are the three sequential biochemical stages carried out by specialized microbial consortia?
A
Hydrolysis, acidogenesis/acetogenesis, and methanogenesis
✓ Correct
B
Nitrification, denitrification, and ammonification
C
Coagulation, flocculation, and sedimentation
D
Oxidation, ozonation, and chlorination
💡 Step-by-Step Explanation & Concept Rationale
Anaerobic sludge digestion proceeds in three discrete stages: (1) Hydrolysis (extracellular breakdown of polymers into monomers), (2) Acidogenesis and Acetogenesis (conversion to volatile fatty acids and acetate/H2), and (3) Methanogenesis (methanogens converting acetate/H2/CO2 into methane gas).
Q. 25 Environmental Sciences
Difficulty: Easy (1 Mark)
What is the typical composition of raw biogas produced during the anaerobic digestion of municipal sewage sludge?
A
~95% Hydrogen, ~5% Nitrogen
B
60-70% Methane (CH4), 30-40% Carbon Dioxide (CO2), and trace H2S
✓ Correct
C
100% Carbon Monoxide
D
80% Oxygen, 20% Ozone
💡 Step-by-Step Explanation & Concept Rationale
Sludge digester biogas typically contains 60% to 70% methane (CH4), 30% to 40% carbon dioxide (CO2), with small fractions of water vapor, nitrogen, hydrogen, and trace hydrogen sulfide (H2S). It has a heating value of ~22-25 MJ/m³.
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